Sol-gel Synthesis, Photo- and Electrocatalytic Properties of Mesoporous TiO2 Modified with Transition Metal Ions
نویسندگان
چکیده
Mesoporous nanosized titania films modified with Co2+, Ni2+, Mn3+, and Cu2+ ions have been produced by templated sol-gel method and characterized by optical spectroscopy, X-ray diffraction (XRD), and Brunauer, Emmett, and Teller (BET) surface area measurement. Band gap energy and the position of flat band potentials were estimated by photoelectrochemical measurements. The films doped with transition metals possessed higher photocurrent quantum yield, as well as photo- and electrochemical activity compared to undoped samples. Mn+/TiO2 (M-Co, Ni, Mn, Cu) electrodes with low dopant content demonstrate high efficiency in electrocatalytic reduction of dissolved oxygen. Polarization curves of TiO2, TiO2/Ni2+, TiO2/Co2+/3+, and TiO2/Mn3+ electrodes contain only one current wave (oxygen reduction current). It means that reaction proceeds without the formation of an intermediate product H2O2.
منابع مشابه
Photocatalytic oxidation of an organophosphorus simulant of chemical warfare agent by modified TiO2 nanophotocatalysts
TiO2 nanoparticles, as a photocatalyst for oxidation of dimethyl methylphosphonate (DMMP) as an organophosphorus simulant of chemical warfare agent, were prepared by using sol-gel method. The prepared nanoparticles were then modified with transition metals in order to decrease the electron-hole recombination and increase the photocatalytic activity. Transition metal ions including Pt...
متن کاملSol-gel Synthesis of ZnO Nanoparticles and ZnO-TiO2-SiO2 Nanocomposites and Their Photo-catalyst Investigation in Methylene Blue Degradation
In this work firstly ZnO nanoparticles were synthesized via a simple precipitation method. At the second step titanium dioxide and silicon dioxide shell were synthesized on the core. For preparation ZnO-TiO2-SiO2 the sol product was calcinated at 500 ºC for 2h. Properties of the product were examined by X-raydiffraction pattern (XRD), scanning electron microscope (SEM) and Fourier transform inf...
متن کاملPhotocatalytic oxidation of an organophosphorus simulant of chemical warfare agent by modified TiO2 nanophotocatalysts
TiO2 nanoparticles, as a photocatalyst for oxidation of dimethyl methylphosphonate (DMMP) as an organophosphorus simulant of chemical warfare agent, were prepared by using sol-gel method. The prepared nanoparticles were then modified with transition metals in order to decrease the electron-hole recombination and increase the photocatalytic activity. Transition metal ions including Pt...
متن کاملSynthesis of TiO2-CuO mesoporous composite nanoparticles by sol-gel method and evaluation of structural, optical and photocatalytic properties
Given the growing importance of photocatalysts in the industrial wastewater treatment, in this study, TiO2-CuO (TC) composite nanoparticles were synthesized by sol-gel method. Tetrabutyl orthotitanate (TBT), copper nitrate-3hydrate and ethanol were used as titanium dioxide precursor, copper oxide precursor and solvent, respectively. The structural, optical, photocatalytic activity and BET-BJH...
متن کاملThe Effect of Surfactant Chain Length and Type on the Photocatalytic Activity of Mesoporous TiO2 Nanoparticles Obtained via Modified Sol-Gel Process
Mesoporous amorphous and nanocrystalline titanium dioxide were prepared by simple and environmental friendly modified Sol-Gel method using cationic (C14TAB, C16TAB, C18TAB) and nonionic (Plantacare UP K55) surfactant as pore forming agent. The obtained particles were characterized by BET, TEM, FT-IR and XRD techniques. The effect of cationic surfactant chain...
متن کامل